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如果在学校,可以进入学校网站的图书资源进行文献检索。其他很多有关的网站要注册会员,免费的不好找,一般都是付费的。
知网或者IEEE都可以的论文——实验结果应高度归纳,精心分析,合乎逻辑地铺述。应该去粗取精,去伪存真,但不能因不符合自己的意图而主观取舍,更不能弄虚作假。只有在技术不熟练或仪器不稳定时期所得的数据、在技术故障或操作错误时所得的数据、不符合实验条件时所得的数据才能废弃不用。而且必须在发现问题当时就在原始记录上注明原因,不能在总结处理时因不合常态而任意剔除。废弃这类数据时应将在同样条件下、同一时期的实验数据一并废弃,不能只废弃不合己意者。实验结果的整理应紧扣主题,删繁就简,有些数据不一定适合于这一篇论文,可留作它用,不要硬行拼凑到一篇论文中。论文行文应尽量采用专业术语。能用表的不要用图,可以不用图表的最好不要用图表,以免多占篇幅,增加排版困难。文、表、图互不重复。实验中的偶然现象和意外变故等特殊情况应作必要的交代,不要随意丢弃。
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知网或者IEEE都可以的论文——实验结果应高度归纳,精心分析,合乎逻辑地铺述。应该去粗取精,去伪存真,但不能因不符合自己的意图而主观取舍,更不能弄虚作假。只有在技术不熟练或仪器不稳定时期所得的数据、在技术故障或操作错误时所得的数据、不符合实验条件时所得的数据才能废弃不用。而且必须在发现问题当时就在原始记录上注明原因,不能在总结处理时因不合常态而任意剔除。废弃这类数据时应将在同样条件下、同一时期的实验数据一并废弃,不能只废弃不合己意者。实验结果的整理应紧扣主题,删繁就简,有些数据不一定适合于这一篇论文,可留作它用,不要硬行拼凑到一篇论文中。论文行文应尽量采用专业术语。能用表的不要用图,可以不用图表的最好不要用图表,以免多占篇幅,增加排版困难。文、表、图互不重复。实验中的偶然现象和意外变故等特殊情况应作必要的交代,不要随意丢弃。
如果在学校,可以进入学校网站的图书资源进行文献检索。其他很多有关的网站要注册会员,免费的不好找,一般都是付费的。
不知道,随便给你一个疏水缔合型聚合物P(AMTA)溶液性质的研究疏水缔合型水溶性聚合物是指在聚合物亲水性大分子链上带有少量疏水基团的一类水溶性聚合物。在聚合物水溶液中,疏水基团之间由于憎水作用而发生聚集,使大分子链产生分子内和分子间缔合。在临界缔合质量分数以上,形成分子间缔合为主的超分子结构,增大了流体力学体积,故具有较好的增黏性。在盐溶液中,由于小分子电解质的加入增加了溶液极性,使疏水缔合作用增强,表现出明显的抗盐性质。 疏水缔合型水溶性高分子很难合成,且不易表征,把疏水部分连接到水溶性聚合物链上,一般采用胶束共聚合或者使用具有表面活性的大单体进行共聚,胶束聚合需要在体系中加入大量的表面活性剂,这就增加了后处理过程的复杂性。利用表面大单体共聚合,需要事先合成大单体,这方面的技术也有相当大的难度。作者采用丙烯酸十四酯作为疏水单体,直接用沉淀聚合法制备疏水缔合型聚合物P(AM/TA)共聚物,从而使共聚反应及其产物的后处理过程较为简单易行。并用凯达尔定氮法表征共聚物的组成,研究共聚物的溶液性能和对苯丙乳液的增稠性。 1实验 1.1试剂 丙烯酰胺(AM),质量分数不少于985%,根据文献提供的方法提纯;N,N-甲基甲酰胺(DMF),分析纯;甲醇、氯化钠,化学纯;丙烯酸十四酯(TA),实验室自制;苯丙乳液由福建省福州树脂有限公司提供。 1.2P(AM/TA)共聚物的合成 称取一定量的AM和TA单体,用DMF溶解,转入三颈瓶中,通氮除氧。升温至80℃,加入引发剂反应4h,过滤,产物用甲醇洗涤多次,以除去未反应的单体。40℃真空干燥至恒重。 1.3分析测试 凯达尔定氮法测定共聚物的组成。用乌氏黏度计测定共聚物溶液特性黏度[η],测试温度为(30±O1)℃。聚合物溶液表观黏度用NDJ-I型旋转黏度计测定。 2结果与讨论 2.1共聚物稀溶液性质不同疏水基团摩尔分数的P(AM/TA)共聚物在蒸馏水和w(NaCl)=5%的溶液中的特性黏度[η]值列于表1。 聚合物的[η]正比于溶液中大分子线团的流体力学体积,因而能反应大分子线团收敛、卷曲的程度。从表1可知,随共聚物的TA链节摩尔分数的增加,其水溶液的[η]值逐渐减小,在w(NaCl)=5%的溶液中也是持续减小。这是因为在稀溶液中,疏水基团缔合以分子内缔合为主,随着TA摩尔分数的增加,分子内缔合增强,导致分子链卷曲。在盐溶液中,由于离子电荷的作用,使疏水链节分子内缔合力增强,分子链收缩,因而[η]值也持续下降。 2.2疏水基团TA摩尔分数对聚合物溶液黏度的影响 图1和图2分别表示P(AM/TA)系列共聚物及PAM在蒸馏水和w(NaCl)=5%的溶液中表观黏度与聚合物质量分数的关系曲线。PAM溶液黏度随其质量分数的增加而平缓上升,而疏水共聚物溶液的质量分数为3O%~4O%时其黏度急剧增加,表明疏水基团聚集而导致分子间缔合,形成了物理交联网络。此时共聚物溶液的质量分数即是临界缔合的质量分数。如图1所示,随TA摩尔分数增加,共聚物溶液的黏度显著增加。当疏水基团摩尔分数较高时,其溶液黏度随质量分数增加的速度更快,共聚物的临界缔合质量分数降低。如图2所示,加入Nacl溶液后,溶液表观黏度有较大提高,如质量分数为O%的P(AM/TA)-1 5聚合物溶液在20℃,转速为6r/min时,黏度达OmPs,而在水溶液中的黏度只有374mPa·s。不同TA摩尔分数的聚合物的质量分数均较其在纯水中低。Hydrophobically associating polymer P (AMTA) the nature of the study solution Hydrophobically associating water-soluble polymer is the hydrophilic polymer with a small amount of macromolecular chain hydrophobic group of a class of water-soluble Aqueous solution in the polymer, the hydrophobic groups and between the role as a result of hydrophobic aggregation occurred, so that large molecules have a molecular chain and inter-molecular Associating the critical mass fraction of the above, the formation of intermolecular association based supramolecular structure, increases the volume of fluid mechanics, it has good by In salt solution, because of the addition of small molecule electrolyte solution increased polarity, so that co-operation with enhanced hydrophobic association, shows that the nature of the Hydrophobically associating water-soluble polymer-based synthesis is difficult and not easily characterized, in part to hydrophobic chains connected to the water-soluble polymer, the general use of micellar copolymerization, or the use of the large surfactant monomer to copolymerization, polymer micelles need in the system by adding a large number of surface-active agent, which, after an increase of the complexity of the The use of the surface monomer copolymerization, the need for prior synthesis of large monomer, this technology also has considerable Author tetradecyl acrylate used as a hydrophobic monomer, the direct use of precipitation polymerization Preparation of hydrophobically associating polymer P (AM / TA) copolymers, so that the product of copolymerization and post-processing is more simple and easy And characterization of nitrogen determination Kedar copolymer composition, study the solution properties of copolymers of styrene-acrylic emulsion and of the 1 Experimental 1 Reagents Acrylamide (AM), the mass fraction of not less than 985 percent, according to documents provided by purification methods; N, N-dimethylformamide (DMF),分析纯; methanol, sodium chloride, chemical pure; acrylic 10 four acetate (TA), laboratory-made; styrene-acrylic emulsion resin from Fuzhou in Fujian Province L 2P (AM / TA) Copolymer Check that a certain amount of monomer AM and TA, using DMF dissolved into three-neck bottle, pass oxygen Warming to 80 ℃, reaction by adding initiator 4h, filtering, washing the product several times with methanol to remove unreacted 40 ℃ vacuum drying to constant 3 Analysis and Testing Determination of nitrogen Kedar will be the composition of Determination of intrinsic viscosity with copolymer solution viscosity [η], the test temperature (30 ± O1) ℃ Apparent viscosity of polymer solution with NDJ-I-type rotary viscometer 2 Results and Discussion 1 Dilute Solution Properties of Copolymers of different mole fraction of hydrophobic groups of the P (AM / TA) copolymers in distilled water, and w (NaCl) = 5% of the solution intrinsic viscosity [η] values listed in Table Polymer [η] is proportional to the solution of the fluid dynamics of macromolecular coil volume, which can respond to the convergence coil macromolecules, the degree of We can see from Table 1, with the copolymer chain of the TA increase in mole fraction, the aqueous solution of [η] value decreases in w (NaCl) = 5% of the solution is continued to This is because in dilute solution, the hydrophobic group to intramolecular association based association, with the mole fraction of the increase in TA, to enhance intramolecular association, resulting in the molecular chain In salt solution, because of the role of ionic charge, so that intramolecular hydrophobic chain to enter into force enhancement, molecular chain contraction, so [η] value continued to TA hydrophobic group 2 mole fraction of polymer solution viscosity on the impact of figures 1 and 2, respectively, P (AM / TA) series of copolymers and PAM in distilled water, and w (NaCl) = 5% in the apparent viscosity of the solution and the relationship between the mass fraction of polymer PAM solution viscosity with the increase of mass fraction of gentle rise, and the hydrophobic copolymer solution for the mass fraction of 3O% ~ 4O%, when a sharp increase in viscosity, indicating that aggregation of hydrophobic groups and lead to intermolecular association, forming a physical crosslinking网络 At this point the mass fraction of copolymer solution that is the critical mass fraction of the As shown in Figure 1, with the mole fraction of TA increased, the viscosity of copolymer solution increased When the mole fraction of hydrophobic groups is high, the solution viscosity increases with the mass fraction of the faster, the critical aggregation copolymer mass fraction As shown in Figure 2, by adding Nacl solution, the solution has greatly enhanced apparent viscosity, such as the mass fraction of O% for the P (AM / TA) -1 5 polymer solution at 20 ℃, rotation speed 6r/min , the viscosity of OmPs, and viscosity in aqueous solution only 374mPa TA different mole fraction of the mass fraction of polymer in water were
不知道,随便给你一个疏水缔合型聚合物P(AMTA)溶液性质的研究疏水缔合型水溶性聚合物是指在聚合物亲水性大分子链上带有少量疏水基团的一类水溶性聚合物。在聚合物水溶液中,疏水基团之间由于憎水作用而发生聚集,使大分子链产生分子内和分子间缔合。在临界缔合质量分数以上,形成分子间缔合为主的超分子结构,增大了流体力学体积,故具有较好的增黏性。在盐溶液中,由于小分子电解质的加入增加了溶液极性,使疏水缔合作用增强,表现出明显的抗盐性质。 疏水缔合型水溶性高分子很难合成,且不易表征,把疏水部分连接到水溶性聚合物链上,一般采用胶束共聚合或者使用具有表面活性的大单体进行共聚,胶束聚合需要在体系中加入大量的表面活性剂,这就增加了后处理过程的复杂性。利用表面大单体共聚合,需要事先合成大单体,这方面的技术也有相当大的难度。作者采用丙烯酸十四酯作为疏水单体,直接用沉淀聚合法制备疏水缔合型聚合物P(AM/TA)共聚物,从而使共聚反应及其产物的后处理过程较为简单易行。并用凯达尔定氮法表征共聚物的组成,研究共聚物的溶液性能和对苯丙乳液的增稠性。 1实验 1.1试剂 丙烯酰胺(AM),质量分数不少于985%,根据文献提供的方法提纯;N,N-甲基甲酰胺(DMF),分析纯;甲醇、氯化钠,化学纯;丙烯酸十四酯(TA),实验室自制;苯丙乳液由福建省福州树脂有限公司提供。 1.2P(AM/TA)共聚物的合成 称取一定量的AM和TA单体,用DMF溶解,转入三颈瓶中,通氮除氧。升温至80℃,加入引发剂反应4h,过滤,产物用甲醇洗涤多次,以除去未反应的单体。40℃真空干燥至恒重。 1.3分析测试 凯达尔定氮法测定共聚物的组成。用乌氏黏度计测定共聚物溶液特性黏度[η],测试温度为(30±O1)℃。聚合物溶液表观黏度用NDJ-I型旋转黏度计测定。 2结果与讨论 2.1共聚物稀溶液性质不同疏水基团摩尔分数的P(AM/TA)共聚物在蒸馏水和w(NaCl)=5%的溶液中的特性黏度[η]值列于表1。 聚合物的[η]正比于溶液中大分子线团的流体力学体积,因而能反应大分子线团收敛、卷曲的程度。从表1可知,随共聚物的TA链节摩尔分数的增加,其水溶液的[η]值逐渐减小,在w(NaCl)=5%的溶液中也是持续减小。这是因为在稀溶液中,疏水基团缔合以分子内缔合为主,随着TA摩尔分数的增加,分子内缔合增强,导致分子链卷曲。在盐溶液中,由于离子电荷的作用,使疏水链节分子内缔合力增强,分子链收缩,因而[η]值也持续下降。 2.2疏水基团TA摩尔分数对聚合物溶液黏度的影响 图1和图2分别表示P(AM/TA)系列共聚物及PAM在蒸馏水和w(NaCl)=5%的溶液中表观黏度与聚合物质量分数的关系曲线。PAM溶液黏度随其质量分数的增加而平缓上升,而疏水共聚物溶液的质量分数为3O%~4O%时其黏度急剧增加,表明疏水基团聚集而导致分子间缔合,形成了物理交联网络。此时共聚物溶液的质量分数即是临界缔合的质量分数。如图1所示,随TA摩尔分数增加,共聚物溶液的黏度显著增加。当疏水基团摩尔分数较高时,其溶液黏度随质量分数增加的速度更快,共聚物的临界缔合质量分数降低。如图2所示,加入Nacl溶液后,溶液表观黏度有较大提高,如质量分数为O%的P(AM/TA)-1 5聚合物溶液在20℃,转速为6r/min时,黏度达OmPs,而在水溶液中的黏度只有374mPa·s。不同TA摩尔分数的聚合物的质量分数均较其在纯水中低。Hydrophobically associating polymer P (AMTA) the nature of the study solution Hydrophobically associating water-soluble polymer is the hydrophilic polymer with a small amount of macromolecular chain hydrophobic group of a class of water-soluble Aqueous solution in the polymer, the hydrophobic groups and between the role as a result of hydrophobic aggregation occurred, so that large molecules have a molecular chain and inter-molecular Associating the critical mass fraction of the above, the formation of intermolecular association based supramolecular structure, increases the volume of fluid mechanics, it has good by In salt solution, because of the addition of small molecule electrolyte solution increased polarity, so that co-operation with enhanced hydrophobic association, shows that the nature of the Hydrophobically associating water-soluble polymer-based synthesis is difficult and not easily characterized, in part to hydrophobic chains connected to the water-soluble polymer, the general use of micellar copolymerization, or the use of the large surfactant monomer to copolymerization, polymer micelles need in the system by adding a large number of surface-active agent, which, after an increase of the complexity of the The use of the surface monomer copolymerization, the need for prior synthesis of large monomer, this technology also has considerable Author tetradecyl acrylate used as a hydrophobic monomer, the direct use of precipitation polymerization Preparation of hydrophobically associating polymer P (AM / TA) copolymers, so that the product of copolymerization and post-processing is more simple and easy And characterization of nitrogen determination Kedar copolymer composition, study the solution properties of copolymers of styrene-acrylic emulsion and of the 1 Experimental 1 Reagents Acrylamide (AM), the mass fraction of not less than 985 percent, according to documents provided by purification methods; N, N-dimethylformamide (DMF),分析纯; methanol, sodium chloride, chemical pure; acrylic 10 four acetate (TA), laboratory-made; styrene-acrylic emulsion resin from Fuzhou in Fujian Province L 2P (AM / TA) Copolymer Check that a certain amount of monomer AM and TA, using DMF dissolved into three-neck bottle, pass oxygen Warming to 80 ℃, reaction by adding initiator 4h, filtering, washing the product several times with methanol to remove unreacted 40 ℃ vacuum drying to constant 3 Analysis and Testing Determination of nitrogen Kedar will be the composition of Determination of intrinsic viscosity with copolymer solution viscosity [η], the test temperature (30 ± O1) ℃ Apparent viscosity of polymer solution with NDJ-I-type rotary viscometer 2 Results and Discussion 1 Dilute Solution Properties of Copolymers of different mole fraction of hydrophobic groups of the P (AM / TA) copolymers in distilled water, and w (NaCl) = 5% of the solution intrinsic viscosity [η] values listed in Table Polymer [η] is proportional to the solution of the fluid dynamics of macromolecular coil volume, which can respond to the convergence coil macromolecules, the degree of We can see from Table 1, with the copolymer chain of the TA increase in mole fraction, the aqueous solution of [η] value decreases in w (NaCl) = 5% of the solution is continued to This is because in dilute solution, the hydrophobic group to intramolecular association based association, with the mole fraction of the increase in TA, to enhance intramolecular association, resulting in the molecular chain In salt solution, because of the role of ionic charge, so that intramolecular hydrophobic chain to enter into force enhancement, molecular chain contraction, so [η] value continued to TA hydrophobic group 2 mole fraction of polymer solution viscosity on the impact of figures 1 and 2, respectively, P (AM / TA) series of copolymers and PAM in distilled water, and w (NaCl) = 5% in the apparent viscosity of the solution and the relationship between the mass fraction of polymer PAM solution viscosity with the increase of mass fraction of gentle rise, and the hydrophobic copolymer solution for the mass fraction of 3O% ~ 4O%, when a sharp increase in viscosity, indicating that aggregation of hydrophobic groups and lead to intermolecular association, forming a physical crosslinking网络 At this point the mass fraction of copolymer solution that is the critical mass fraction of the As shown in Figure 1, with the mole fraction of TA increased, the viscosity of copolymer solution increased When the mole fraction of hydrophobic groups is high, the solution viscosity increases with the mass fraction of the faster, the critical aggregation copolymer mass fraction As shown in Figure 2, by adding Nacl solution, the solution has greatly enhanced apparent viscosity, such as the mass fraction of O% for the P (AM / TA) -1 5 polymer solution at 20 ℃, rotation speed 6r/min , the viscosity of OmPs, and viscosity in aqueous solution only 374mPa TA different mole fraction of the mass fraction of polymer in water were
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美国化学学会
权威的还是中国知网、万方数据库、维普数据、龙源等等,不过这些都要收费的查看原帖>>
一PubmedPubmed是美国国家医学图书馆(NLM)所属的国家生物技术信息中心(NCBI)于2000年4月开发的一个基于WEB的生物医学信息检索系统。二seek68文献馆seek68文献馆是中外文献数据库资源整合检索平台。覆盖各科领域,包括医学的各个分类。可以全文阅读下载。三JAMA美国医学会(American Medical Association, AMA)创建于1847年,是世界三大医学会之一,其拥有发行的JAMA系列电子期刊,共12种,刊载医学领域优秀论文和最新动态,在业界享有盛誉。四hieme德国Thieme出版社是一家拥有百年历史的医学和科学出版社。包含130多种以纸本形式和电子版本的医学和科学期刊,其中60多种是代表各专业学会出版的。五KargerKarger出版的学科领域涵盖了医学的传统领域及现代医学的最新发展,从肿瘤学、内分泌学、肾脏学、细胞生物学、神经系统科、血液学到遗传学,读者都可以从Karger的书籍或者期刊中得到所有生物医学领域最新的发展、应用及研究信息。六HighWire PressHighWire Press是全球最大的提供免费全文的学术文献出版商。现提供1300余种期刊,涵盖生物科学、人文、医学、物理科学、社会科学等大类。标为free的可免费访问全文。七ClinicalKey临床精钥是信息分析公司爱思唯尔(Elsevier)推出的一个临床决策支持工具,帮助医生快速获取准确、简洁、世界前沿的循证医学知识。八Clinical trials提供了网站临床试验注册辅导,登记了各种观察性研究和干预性研究,包括药物、器械和手术等干预方式。其注册和查询临床试验均为免费~九Cochrane libra它包含以下6个数据库 ?Cochrane Database of Systematic Review(医学保健领域系统评估的领先资源)Cochrane 临床对照实验数据库Cochrane Methodology Register(介绍进行对照试验时所用方法的参考出版物)Health Technology Assessment Database(卫生技术评估)NHS Economic Evaluation Datab6(经济评估数据库)About The Cochrane Collaboration(组成Cochrane Collaboration的80个组织的信息)十EMBASE内容涉及药学、临床医学、基础医学、预防医学、法医学和生物医学工程等。十一OVIDOvid(Ovid Technologies)在国外医学界被广泛应用。其Databases@Ovid包括300多种医学外文文献数据库,并可直接链接全文期刊和馆藏。十二UpToDate数据库UpToDate数据库是用于协助临床医生进行诊疗上的判断、决策的循证医学数据库。覆盖了常见的25 个临床专科,涵盖了诊疗全流程和生命全周期的绝大多数疾病及其相关问题,目前已收录10500多篇临床专题。
一PubmedPubmed是美国国家医学图书馆(NLM)所属的国家生物技术信息中心(NCBI)于2000年4月开发的一个基于WEB的生物医学信息检索系统。二seek68文献馆seek68文献馆是中外文献数据库资源整合检索平台。覆盖各科领域,包括医学的各个分类。可以全文阅读下载。三JAMA美国医学会(American Medical Association, AMA)创建于1847年,是世界三大医学会之一,其拥有发行的JAMA系列电子期刊,共12种,刊载医学领域优秀论文和最新动态,在业界享有盛誉。四hieme德国Thieme出版社是一家拥有百年历史的医学和科学出版社。包含130多种以纸本形式和电子版本的医学和科学期刊,其中60多种是代表各专业学会出版的。五KargerKarger出版的学科领域涵盖了医学的传统领域及现代医学的最新发展,从肿瘤学、内分泌学、肾脏学、细胞生物学、神经系统科、血液学到遗传学,读者都可以从Karger的书籍或者期刊中得到所有生物医学领域最新的发展、应用及研究信息。六HighWire PressHighWire Press是全球最大的提供免费全文的学术文献出版商。现提供1300余种期刊,涵盖生物科学、人文、医学、物理科学、社会科学等大类。标为free的可免费访问全文。七ClinicalKey临床精钥是信息分析公司爱思唯尔(Elsevier)推出的一个临床决策支持工具,帮助医生快速获取准确、简洁、世界前沿的循证医学知识。八Clinical trials提供了网站临床试验注册辅导,登记了各种观察性研究和干预性研究,包括药物、器械和手术等干预方式。其注册和查询临床试验均为免费~九Cochrane libra它包含以下6个数据库 ?Cochrane Database of Systematic Review(医学保健领域系统评估的领先资源)Cochrane 临床对照实验数据库Cochrane Methodology Register(介绍进行对照试验时所用方法的参考出版物)Health Technology Assessment Database(卫生技术评估)NHS Economic Evaluation Datab6(经济评估数据库)About The Cochrane Collaboration(组成Cochrane Collaboration的80个组织的信息)十EMBASE内容涉及药学、临床医学、基础医学、预防医学、法医学和生物医学工程等。十一OVIDOvid(Ovid Technologies)在国外医学界被广泛应用。其Databases@Ovid包括300多种医学外文文献数据库,并可直接链接全文期刊和馆藏。十二UpToDate数据库UpToDate数据库是用于协助临床医生进行诊疗上的判断、决策的循证医学数据库。覆盖了常见的25 个临床专科,涵盖了诊疗全流程和生命全周期的绝大多数疾病及其相关问题,目前已收录10500多篇临床专题。
可以看看(临床医学进展、医学诊断)这类OA刊物
1、医学生应该常去的网站有:医学生: 、医学生论坛:、中国解剖网: -/、医学生家园: 、医学考研网: 等。2、医学生是一个面向医学专业的学生及从医人员方面的专业。3、医学,是通过科学或技术的手段处理人体的各种疾病或病变。它是生物学的应用学科,分基础医学、临床医学。从解剖层面和分子遗传层面来处理人体疾病的高级科学。它是一个从预防到治疗疾病的系统学科,研究领域大方向包括基础医学、临床医学、法医学、检验医学、预防医学、保健医学、康复医学等。
别人又不知道你的基础和学习能力自己做套真题,估下自己的分数对比往年复试分数就能知道好不好考了